A Laboratory Preparation of High-Purity Calcium Cyanamide

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Abstract

Calcium cyanamide is an important fertilizer and a chemical precursor. However, its large scale synthesis is extremely energy intensive via the historical Frank-Caro synthesis of fixing atmospheric nitrogen with calcium carbide at an elevated temperature, and the product material contains a large number of impurities. In this work, we prepare calcium cyanamide in a purity higher than that achievable by the Frank-Caro route in a convenient laboratory method.

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Klimek, A., Yount, J., Wozniak, D., Zeller, M., & Piercey, D. G. (2023). A Laboratory Preparation of High-Purity Calcium Cyanamide. Inorganic Chemistry, 62(40), 16280–16282. https://doi.org/10.1021/acs.inorgchem.3c02235

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