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Site-Selectivity in the Cyanation of 3-Substituted Pyridine 1-Oxides with Trimethylsilanecarbonitrile

Chemical and Pharmaceutical Bulletin (1985) 33(2) 565-571
DOI: 10.1248/cpb.33.565
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Abstract

The cyanation of 3-halo-, 3-methoxy-, and 3-dimethylaminopyridine 1-oxide with trimethyl-silanecarbonitrile gave predominantly the corresponding 3-substituted 2-pyridinecarbonitriles. The deoxygenation of nitropyridine 1-oxides to nitropyridines with the same reagent is also described. © 1985, The Pharmaceutical Society of Japan. All rights reserved.

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Sakamoto, T., Kaneda, S., Nishimura, S., & Yamanaka, H. (1985). Site-Selectivity in the Cyanation of 3-Substituted Pyridine 1-Oxides with Trimethylsilanecarbonitrile. Chemical and Pharmaceutical Bulletin, 33(2), 565–571. https://doi.org/10.1248/cpb.33.565

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