Artificial Neural Network (ANN) Modeling for Prediction of Pesticide Wastewater Degradation by FeGAC/H2O2 Process

Abstract

The study examined artificial neural network (ANN) modeling for the prediction of chlorpyrifos, cypermethrin and chlorothalonil pesticides degradation by the FeGAC/H2O2 process. The operating condition was the optimum condition from a series of experiments. Under these conditions; FeGAC 5 g/L, H2O2 concentration 100 mg/L, pH 3 and 60 min reaction time, the COD removal obtained was 96.19%. The ANN model was developed using a three-layer multilayer perceptron (MLP) neural network to predict pesticide degradation in terms of COD removal. The configuration of the model with the smallest mean square error (MSE) of 0.000046 contained 5 inputs, 9 hidden and, 1 output neuron. The Levenberg-Marquardt backpropagation training algorithm was used for training the network, while tangent sigmoid and linear transfer functions were used at the hidden and output neurons, respectively. The predicted results were in close agreement with the experimental results with correlation coefficient (R2) of 0.9994 i.e. 99.94% showing a close agreement to the actual experimental results. The sensitivity analysis showed that FeGAC dose had the highest influence with relative importance of 25.33%. The results show how robust the ANN model could be in the prediction of the behavior of the FeGAC/H2O2 process.