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Electronic, steric and catalytic properties of N-heterocyclic carbene rhodium(i) complexes linked to (metallo)porphyrins

Chemical Communications (2022) 58(95) 13270-13273
DOI: 10.1039/d2cc05547c
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Abstract

Electronic and steric properties of NHC ligands functionalized with porphyrins were investigated. When porphyrins are used as NHC-wingtips, nickel(ii) in the macrocyle significantly improves the catalytic activity of the neighbouring NHC-Rh(i) complex in the conjugate addition of phenylboronic acid to cyclohexen-2-one.

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APA

Poyac, L., Scoditti, S., Dumail, X., Granier, M., Clément, S., Gramage-Doria, R., … Richeter, S. (2022). Electronic, steric and catalytic properties of N-heterocyclic carbene rhodium(i) complexes linked to (metallo)porphyrins. Chemical Communications, 58(95), 13270–13273. https://doi.org/10.1039/d2cc05547c

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