(3R,4S)-3,4-Isopropylidenedioxy-3,4-dihydro-2H-pyrrole 1-oxide

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Abstract

The title compound C7H11NO3 was prepared by intramolecular nucleophilic displacement of 2,3-O-iso-propylidene-d- erythronolactol. There are two molecules in the asymmetric unit, which are related by a pseudo-inversion centre. The crystal structure determination confirms unequivocally the configuration of the chiral centres as 3S,4R. In the crystal structure, intermolecular C-H⋯O interactions link the molecules (into infinite zigzag chains along the a axis.

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Fe Flores, M., Garcia, P., Garrido, N. M., Sanz, F., & Dieza, D. (2011). (3R,4S)-3,4-Isopropylidenedioxy-3,4-dihydro-2H-pyrrole 1-oxide. Acta Crystallographica Section E: Structure Reports Online, 67(5). https://doi.org/10.1107/S1600536811013055

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