Formal synthesis of teleocidin a via indole-Cr(CO)3 complexes

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Abstract

The addition of a cyano-stabilized anion to a 4-aminoindole-Cr(CO)3 complex can be directed to selective C-7 substitution, and the resulting intermediate is part of a formal total synthesis of teleocidin A1/A2. © 1993.

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Semmelhack, M. F., & Rhee, H. (1993). Formal synthesis of teleocidin a via indole-Cr(CO)3 complexes. Tetrahedron Letters, 34(9), 1399–1402. https://doi.org/10.1016/S0040-4039(00)60301-5

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