Symmetry breaking and structure of a mixture of nematic liquid crystals and anisotropic nanoparticles

Abstract

Orientational ordering of a homogeneous mixture of uniaxial liquid crystalline (LC) molecules and magnetic nanoparticles (NPs) is studied using the Lebwohl-Lasher lattice model. We consider cases where NPs tend to be oriented perpendicularly to LC molecules due to elastic forces. We study domain-type configurations of ensembles, which are quenched from the isotropic phase. We show that for large enough concentrations of NPs the long range uniaxial nematic ordering is replaced by short range order exhibiting strong biaxiality. This suggests that the impact of NPs on orientational ordering of LCs for appropriate concentrations of NPs is reminiscent to the influence of quenched random fields which locally enforce a biaxial ordering. © 2010 Krasna et al; licensee Beilstein-Institut.