Two-dimensional orbital ordering in d1 Mott insulator Sr 2VO4

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Abstract

The Mott insulator Sr2VO4 is a unique d1 two-dimensional compound exhibiting an orbital ordering transition. In addition to the orbital ordering transition at about 100 K, we discovered a ferromagnetic transition below 10 K, thus confirming the predictions of recent band structure calculations. The magnetic properties proved to be strongly sensitive to the material purity, the actual oxygen stoichiometry and the crystallographic parameters. An additional transition is observed at 125 K, which is believed to be due to structural modifications. © 2010 IOP Publishing Ltd.

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Viennois, R., Giannini, E., Teyssier, J., Elia, J., Deisenhofer, J., & Van Der Marel, D. (2010). Two-dimensional orbital ordering in d1 Mott insulator Sr 2VO4. In Journal of Physics: Conference Series (Vol. 200). Institute of Physics Publishing. https://doi.org/10.1088/1742-6596/200/1/012219

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