Investigations of ion transport through nanoscale polymer membranes by fluorescence quenching of CdSe/CdS quantum dot/quantum rods

Abstract

Detailed steady-state and time-resolved fluorescence quenching measurements give deep insight into ion transport through nanometer thick diblock copolymer membranes, which were assembled as biocompatible shell material around CdSe/CdS quantum dot in quantum rods. We discuss the role of polymer chain length, intermolecular cross-linking and nanopore formation by analysing electron transfer processes from the photoexcited QDQRs to Cu(ii) ions, which accumulate in the polymer membrane. Fluorescence investigations on single particle level additionally allow identifying ensemble inhomogeneities.