Recent progress in self-healing polyurethanes based on Diels-Alder reaction

Abstract

This review examines the latest advances in the synthesis and application of polyurethanes that have a self-healing effect due to the thermally reversible Diels-Alder reaction. A classification of strategies for improving the parameters of the final polymers is proposed, which includes the division into polyurethanes with a flexible organic linker, composites with nanoparticles, and systems with a dual self-healing mechanism both due to the Diels-Alder reaction and the reaction of the formation of a disulfide bonds from thiols. The possible applications of the obtained materials and the assumption about the further development of the field are considered.