[(1R,2R)-2-Amino-1,2-diphenyl-N-(p-tolylsulfonyl)ethylamido] chloro(η6-ethoxybenzene)ruthenium(II) methanol solvate

Janet Soleimannejad; Harry Adams; Colin White

Journal ArticleOPEN ACCESS

[(1R,2R)-2-Amino-1,2-diphenyl-N-(p-tolylsulfonyl)ethylamido] chloro(η6-ethoxybenzene)ruthenium(II) methanol solvate

Acta Crystallographica Section C: Crystal Structure Communications (2005) 61(3)

DOI: 10.1107/S0108270104033815

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Abstract

r The title compound, [Ru(C21H21N2O 2S)Cl(C8H10O)]·CH4O or [Ru(TsDPEN)Cl(η6-C6H5OCH2CH 3)]·CH4O [where TsDPEN is (1R,2R)-1,2-diphenyl-N- (p-toluenesulfonyl)ethylenediamine], contains an S-chiral Ru centre in a distorted octahedral environment, with similar bond lengths and angles to analogous complexes. The very short (N-)H⋯Cl distance of 2.61 Å is ascribed to an intramolecular hydrogen bond. © 2005 International Union of Crystallography.

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Soleimannejad, J., Adams, H., & White, C. (2005). [(1R,2R)-2-Amino-1,2-diphenyl-N-(p-tolylsulfonyl)ethylamido] chloro(η6-ethoxybenzene)ruthenium(II) methanol solvate. Acta Crystallographica Section C: Crystal Structure Communications, 61(3). https://doi.org/10.1107/S0108270104033815

[(1R,2R)-2-Amino-1,2-diphenyl-N-(p-tolylsulfonyl)ethylamido] chloro(η6-ethoxybenzene)ruthenium(II) methanol solvate

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