A new “bicycle helmet”-like copper(ii),sodiumphenylsilsesquioxane. Synthesis, structure and catalytic activity

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Abstract

A new “bicycle helmet”-like copper(ii),sodiumphenylsilsesquioxane Ph12Si12O12(OH)(O−)11Cu5Na(bipy)3(H2O) exhibited high catalytic efficiency in two homogeneous reactions: (i) functionalization of C-H compounds; (ii) formation of benzamides from alcohols.

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Kulakova, A. N., Bilyachenko, A. N., Korlyukov, A. A., Shul’pina, L. S., Bantreil, X., Lamaty, F., … Shul’pin, G. B. (2018). A new “bicycle helmet”-like copper(ii),sodiumphenylsilsesquioxane. Synthesis, structure and catalytic activity. Dalton Transactions, 47(44), 15666–15669. https://doi.org/10.1039/c8dt03209b

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