The crystal structure of the Dess-Martin periodinane

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Abstract

We report the elusive X-ray structure of the Dess-Martin periodinane (DMP), a hypervalent iodine reagent popular amongst synthetic chemists. In the solid state, the highly crystalline compound forms an intricate coordination polymer held together by intermolecular halogen and hydrogen bonds. © 2012 Schröckeneder et al; licensee Beilstein-Institut.

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Schröckeneder, A., Stichnoth, D., Mayer, P., & Trauner, D. (2012). The crystal structure of the Dess-Martin periodinane. Beilstein Journal of Organic Chemistry, 8, 1523–1527. https://doi.org/10.3762/bjoc.8.172

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