Halogenation using quaternary ammonium polyhalides. XIV. Aromatic bromination and iodination of arenes by use of benzyltrimethylammonium polyhalides-zinc chloride system

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Abstract

The reaction of arenes with benzyltrimethylammonium tribromide or benzyltrimethylammonium dichlo-roiodate in acetic acid in the presence of ZnCl2 at room temperature or at 70 °C gave bromo- or iodo-substituted arenes in good yield, respectively.

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Kajigaeshi, S., Kakinami, T., Moriwaki, M., Tanaka, T., Fujisaki, S., & Okamoto, T. (1989). Halogenation using quaternary ammonium polyhalides. XIV. Aromatic bromination and iodination of arenes by use of benzyltrimethylammonium polyhalides-zinc chloride system. Bulletin of the Chemical Society of Japan, 62(2), 439–443. https://doi.org/10.1246/bcsj.62.439

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