Tetraceno[2,1,12,11-opqra]tetracene-extended tetrathiafulvalene-redox-controlled generation of a large PAH core

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Abstract

Two tetraceno[2,1,12,11-opqra]tetracene-extended tetrathia-fulvalenes were prepared and found to undergo reversible conversion into their planar polycyclic aromatic hydrocarbons (PAHs) upon electrochemical oxidation-at potentials probing the best valence bond representations.

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Broman, S. L., Andersen, C. L., Jousselin-Oba, T., Mansø, M., Hammerich, O., Frigoli, M., & Nielsen, M. B. (2017). Tetraceno[2,1,12,11-opqra]tetracene-extended tetrathiafulvalene-redox-controlled generation of a large PAH core. Organic and Biomolecular Chemistry, 15(4), 807–811. https://doi.org/10.1039/c6ob02666d

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