Synthesis and characterisation of new 2-diazo-3-oxo-5,10,15,20-tetraphenylchlorins

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Abstract

The Cu and Ni derivatives of β-amino-5,10,15,20-tetraphenylporphyrin react with sodium nitrite in THF by formation of 2-diazo-3-oxo-5,10,15,20-tetraphenylchlorins. The spectroscopic properties and some electrochemical properties of the synthesised compounds were investigated.

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Cavaleiro, J. A. S., Gerdan, V. M., Hombrecher, H. K., Neves, M. G. P. M. S., & Silva, A. M. S. (1997). Synthesis and characterisation of new 2-diazo-3-oxo-5,10,15,20-tetraphenylchlorins. Heterocyclic Communications, 3(3), 253–261. https://doi.org/10.1515/hc.1997.3.3.253

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