Kinetic adsorption of methyl blue dye from aqueous solution by PVC/PVC-based copolymer containing quaternary amine

Abstract

The present study has investigated the use of a blend polymer polyvinyl chloride/polyvinyl chloride-graft-poly[2-(dimethylamino) ethyl methacrylate containing a quaternary amine in its structure (PVC/PVC-g-PDMAEM(N+)) as an adsorbent for the removal of methyl blue dye from aqueous solution. The synthesized polymer blend has been characterized by Fourier Transform Infrared Spectroscopy (FT-IR), scanning Electron Microscope-energy-dispersive spectroscopy (SEM–EDX), and the scanning Spectrophotometer Ultraviolet–visible (UV–Vis). The adsorption studies have been performed by batch experiments. Moreover, the pH effect, adsorbent dose, initial dye concentration, and contact time effect have been explored. Furthermore, the kinetic experimental data have been analyzed using pseudo-first and pseudo-second-order models. The results have shown that the adsorption process is more described by the pseudo-second-order model with a high determination coefficient. The equilibrium adsorption data have been analyzed using three widely applied isotherms: Langmuir, Freundlich, and Tempkin. The best fit was found to be Freundlich isotherm with maximum monolayer adsorption of Methyl Blue (MB) equal to 142.86 mg/g, which was observed at pH = 7. The results have indicated that the PVC/PVC-g-PDMAEM(N+) blend polymer is an efficient adsorbent for removing anionic dyes from wastewater. Graphical Abstract: [Figure not available: see fulltext.]