Abstract
Novel, chiral Lewis base organocatalysts, which displayed poor enantioselection in the hydrosilylation of N-aryl β-enamino esters, were found to be the catalysts of choice in the hydrosilylation of a-imino esters. In the presence of 10mol-% of the best catalyst, various a-imino esters under-went enantioselective hydrosilylation to provide a wide range of chiral a-amino esters with good, yields (up to 97%) and high enantioselectivities (up to 93 % ee) except for some special substrates. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
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Xue, Z. Y., Jiang, Y., Yuan, W. C., & Zhang, X. M. (2010). The first highly enantioselective lewis base organocatalyzed hydrosilylation of α-Imino esters. European Journal of Organic Chemistry, (4), 616–619. https://doi.org/10.1002/ejoc.200901312
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