Abstract
In a convenient one-pot process, the easily accessible 1,2-diaza-1,3- butadienes and 1,3-bis(silyl enol ethers) are converted into the previously unknown functionalized 1-aminopyrroles and 1-amino-4,5,6,7-tetrahydroindoles. The domino reaction proceeds through a zinc chloride-catalyzed Econjugate addition/cyclizationG sequence. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
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Karapetyan, V., Mkrtchyan, S., Schmidt, A., Attanasi, O. A., Favi, G., Mantellini, F., … Langer, P. (2008). Diversity-oriented synthesis of functionalized 1-aminopyrroles by regioselective zinc chloride-catalyzed, one-pot “conjugate addition/cyclization” reactions of 1,3-bis(silyl enol ethers) with 1,2-diaza-1,3-butadienes. Advanced Synthesis and Catalysis, 350(9), 1331–1336. https://doi.org/10.1002/adsc.200800097
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