Surface Plasmon Resonance and Increased Interfacial Electron Transfer of 3D AgNWS@TiO2NS Structure for Enhanced Photocatalytic and DSSC Properties

Abstract

Ag nanowires coated with TiO2 nanosheets (AgNWS@TiO2NS, AWT) have been successfully synthesized via a one-pot hydrothermal synthesis. Importantly, the prepared AWT shows enhanced photocatalytic activity compared with Degussa P25, which is attributed to its continuous hierarchical structures, special conductive channel and localized surface plasmon resonance (SPR). Additionally, these prepared AWT were exploited as an electron conductor and scattering material in the TiO2 composite photoanodes of dye-sensitized solar cells (DSSCs). The highest energy conversion efficiency of 6.98% was achieved when the AWT doping rate in the photoanode slurry was 5 wt%. Both enhanced Isc and Voc are attributed to the increased photo-absorption efficiency from the localized SPR. The potential enhanced light-scattering effect and faster photoelectric transmission efficiency of the AWT in the photoanode.