Abstract
(Chemical Equation Presented) An unprecedented oxidation of chromium(II) by trimethylaluminum which, despite the reducing environment, forms a cationic organochromium(III) complex (see picture; SNS = RSCH2CH 2N(H)-CH2CH2SR, Cy = cyclohexyl, X = [Me 6Al2Cl]), provides a possible catalyst re-activation pathway. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
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Temple, C., Jabri, A., Crewdson, P., Gambarotta, S., Korobkov, I., & Duchateau, R. (2006). The question of the Cr oxidation state in the {Cr(SNS)} catalyst for selective ethylene trimerization: An unanticipated re-oxidation pathway. Angewandte Chemie - International Edition, 45(42), 7050–7053. https://doi.org/10.1002/anie.200602240
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