Two organometallic catalysis studies are presented. The first one deals with the development of a new catalytic agent based on the mixture of a hydride and an iron salt to trigger efficient radical cyclization processes. In a second line of research, we have shown that the use of chiral anions can outperform chiral ligands in a carbocyclization reaction and a [2 + 2 + 2] cycloaddition. © 2014 IUPAC.
CITATION STYLE
Aubert, C., Barbazanges, M., Jutand, A., Kyne, S. H., Ollivier, C., & Fensterbank, L. (2014). Organometallic catalysis for applications in radical chemistry and asymmetric synthesis. In Pure and Applied Chemistry (Vol. 86, pp. 273–281). IUPAC Secretariat. https://doi.org/10.1515/pac-2014-5030
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