Abstract
Self-assembly of a trigonal building subunit with diaminotriazines (DAT) functional groups leads to a unique rod-packing 3D microporous hydrogen-bonded organic framework (HOF-3). This material shows permanent porosity and demonstrates highly selective separation of C2H2/CO2 at ambient temperature and pressure.
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Li, P., He, Y., Zhao, Y., Weng, L., Wang, H., Krishna, R., … Chen, B. (2015). A rod-packing microporous hydrogen-bonded organic framework for highly selective separation of C2H2/CO2at room temperature. Angewandte Chemie - International Edition, 54(2), 574–577. https://doi.org/10.1002/anie.201410077
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