Slow magnetic relaxation in uranium(III) and neodymium(III) cyclooctatetraenyl complexes

Abstract

The synthesis, structure, and magnetic properties of a uranium(III) sandwich complex, [Li(DME) 3 ][U III (COT") 2 ] (COT" = bis(trimethylsilyl)cyclooctatetraenyl dianion), and its coordinatively analogous tetravalent equivalent, [U IV (COT") 2 ], were investigated. Additionally, a full structural and magnetic comparison to the isostructural and isoelectronic lanthanide complex, [Li(DME) 3 ][Nd III (COT") 2 ], is provided. DFT calculations reveal that the U III complex leads to weaker ligand-to-metal donation as compared with the tetravalent equivalent complex. Alternating current magnetic susceptibility results reveal slow magnetic relaxation in both U III and Nd III complexes. The enhanced magnetic performance of the U III congener further encourages the use of actinides in the design of single-molecule magnets.