The distribution behavior of elements during the top-blowing smelting process of electronic waste

Abstract

In this work, the local equilibrium modeling method of a non-equilibrium multi-phase reaction system in the top-blowing melting process of electronic waste was studied. The automatic judgment mechanism of phase transformation and the improvement of the trace component solving algorithm were explored to build the mathematical model of the element migration and transformation. Secondly, to determine the distribution mechanism of various elements in top-blowing smelting of electronic waste, the thermodynamic digital simulation system was developed according to the software platform of metallurgical process calculation. On this basis, combined with the industrial production practice, the coupling simulation experiment was carried out to investigate the influence of oxygen:feed ratio, oxygen concentration, amount of additive iron powder and CaO:SiO2 ratio of the slag on the smelting process. In addition, the direct yields of metals in the slag were Cu 90.69 wt%, Au 98.57 wt%, Ag 94.84 wt%, and Pd 97.87 wt% under the optimum conditions. Finally, the simulated values were consistent with industrial data, which can provide theoretical guidance for the industrial production practice of the top-blowing smelting of electronic waste.