Noble gas mass spectrometry with a compressor driven recycling system for improved sensitivity

Abstract

In order to increase the sensitivity of static-mode noble gas mass spectroscopic analysis, we have developed and tested a gas re-circulation system, which uses a commercially available turbo molecular pump (TMP). During the analysis, the sample gases are directed from the collector end towards the ionization source part of the flight tube. Our preliminary results indicate that the apparent sensitivity of krypton and xenon can be increased by a factor of about 20 and 50, respectively. We also found that the gain factor of helium was somewhat smaller and was approximately 2. Such mass-dependence is quite consistent with the compressibility of TMP which is larger for the heavier molecules. Copyright © 2010 by The Geochemical Society of Japan.