Reducing the uncertainty caused by the laser spot radius in frequency-domain thermoreflectance measurements of thermal properties

Abstract

In a frequency-domain thermoreflectance (FDTR) experiment, the phase lag between the surface temperature response and the applied heat flux is fit with an analytical solution to the heat diffusion equation to extract an unknown thermal property (e.g., thermal conductivity) of a test sample. A method is proposed to reduce the impact of uncertainty in the laser spot radius on the resulting uncertainty in the fitted property that is based on fitting to the quotient of the test sample phase and that of a reference sample. The reduction is proven analytically for a semi-infinite solid and was confirmed using numerical and real experiments on realistic samples. When the spot radius and its uncertainty are well known, the reference phase can be generated numerically. In this situation, FDTR experiments performed on Au-SiO2-Si and PbS nanocrystal test samples demonstrate 32% and 82% reductions in the overall uncertainty in thermal conductivity. When the spot radius used in the test sample measurement is not well known, a real reference sample, measured under conditions that lead to the same unknown spot radius, is required. Although the real reference sample introduces its own uncertainties, the total uncertainty in the fitted thermal conductivity can still be reduced. A reference sample can also be used to reduce uncertainty due to other sources, such as the transducer properties. Because frequency-domain solutions to the heat diffusion equation are the basis for time-domain thermoreflectance (TDTR) analysis, the approach can be extended to TDTR experiments.