Non-electronic gas sensors from electrospun mats of liquid crystal core fibres for detecting volatile organic compounds at room temperature

Abstract

Non-woven mats comprised of liquid crystal-functionalised fibres are coaxially electrospun to create soft gas sensors that function non-electronically, thus requiring no power supply, detecting organic vapours at room temperature. The fibres consist of a poly(vinylpyrrolidone) (PVP) sheath surrounding a core of nematic 4-cyano-4ʹpentylbiphenyl (5CB) liquid crystal. Several types of mats, containing uniformly cylindrical or irregular beaded fibres, in uniform or random orientations, are exposed to toluene vapour as a representative volatile organic compound. Between crossed polarisers all mats respond with a fast (response time on the order of a second or faster) reduction in brightness during gas exposure, and they return to the original state upon removal of the gas almost as quickly. With beaded fibres, the response of the mats is visible even without polarisers. We discuss how variations in fibre spinning conditions such as humidity level and the ratio of core-sheath fluid flow rates can be used to tune fibre morphology and thereby the response. Considering future development perspectives, we argue that fibres turned responsive through the incorporation of a liquid crystal core show promise as a new generation of sensors with textile form factor, ideal for wearable technology applications.