Facile Synthesis of Sulfate-Intercalated CoFe LDH Nanosheets Derived from Two-Dimensional ZIF-9(III) for Promoted Oxygen Evolution Reaction

Abstract

Layered double hydroxide (LDH) has emerged as a promising electrocatalyst; however, the synthetic method usually requires high temperature and high pressure, and sulfate-intercalated LDH is rarely reported. Herein, the sulfate-intercalated CoFe LDH nanosheets were successfully fabricated at ambient temperature via a facile strategy, using two-dimensional ZIF-9(III) as a template and FeSO4 as both etchant and iron source. When the as-prepared sulfate-intercalated CoFe LDH acts as an electrocatalyst, it presents superior electrocatalytic performance for the oxygen evolution reaction (OER), requiring low overpotential (η@10 mA cm−2 = 218 mV) with a small Tafel slope of 59.9 mV dec−1 in 1.0 M KOH, which compares favorably with commercial RuO2 and most reported transition-metal electrocatalysts. The high catalytic activity of CoFe LDH might be ascribed to the large interlayer space distance originating from special SO42− ions and the strong synergistic effects between Fe and Co. This work provides a novel and feasible approach to designing highly efficient electrocatalysts based on advanced LDH materials for OER.