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Readily available onio-substituted methyleneiminium salts: Single precursors for a variety of aminocarbenes

Angewandte Chemie - International Edition (2004) 43(31) 4089-4093
DOI: 10.1002/anie.200460045
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Abstract

From amides to carbenes: Phosphonio-substituted iminium salts are readily available from the corresponding amides in a one-pot reaction. Deprotonation followed by substitution reactions affords a variety of transient and stable amino carbenes (see scheme).

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Conejero, S., Canac, Y., Tham, F. S., & Bertrand, G. (2004). Readily available onio-substituted methyleneiminium salts: Single precursors for a variety of aminocarbenes. Angewandte Chemie - International Edition, 43(31), 4089–4093. https://doi.org/10.1002/anie.200460045

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