TiO2 Nanoparticles Obtained by Green Synthesis: Characterization and Evaluation of Their Effect on the Self-Cleaning and Antifungal Properties of an Aqueous Paint-Type Coating

Abstract

This work presents a green chemistry route to obtain titanium dioxide TiO2 nanoparticles with an average size of about 13.25 nm using lemongrass (Cymbopogon citratus) extract. For these assessments, TiO2 nanoparticles were added to the coating at concentrations of 1% and 5% w/w on fiber-cement sheets. Self-cleaning evaluation was analyzed by the photodegradation of methylene blue (MB) dye at concentrations of 5, 10, and 20 mg/L applied to the coated sheet, and then exposed to simulated sunlight. The coating containing 5 wt% TiO2 nanoparticles showed the highest photodegradation, reaching 93.3% after 4 h under simulated sunlight exposure at the lowest MB concentration (5 mg/L). Additionally, average contact angles of 80.4°, 92.03°, and 104.25° were determined for coatings containing 0%, 1%, and 5 wt% TiO2, respectively. Moreover, the modified 5 wt% TiO2 exhibited up to 30.9% greater hydrophobicity than the control. Antifungal efficacy against Aspergillus niger and Penicillium was evaluated using the Poisoned Food method with nanoparticles at concentrations of 1 and 3 mg/mL showing a moderate growth inhibition. In conclusion, the versatility demonstrated suggests potential applications such as a nano-additive for aqueous acrylic coatings, improving hydrophobicity, self-cleaning and antifungal properties, which could be attractive to the construction industry.