Equilibrium and kinetics studies of metal ions biosorption on alginate extracted from marine red algae biomass (Callithamnion corymbosum sp.)

Abstract

Biosorption is a viable alternative that can be used to remove heavy metal ions from aqueous effluents, as long as the biosorbent used is cost-effective and efficient. To highlight this aspect in this study, alginate extracted from marine red algae biomass (Callithamnion corymbosum sp.) was used as biosorbent for the removal of Cu(II), Co(II) and Zn(II) ions from aqueous media. Biosorption studies were performed in a batch system, and the biosorptive performances of the alginate were examined as function of initial solution pH, biosorbent dosage, contact time, initial metal ions concentration and temperature. The optimal experimental conditions were found: initial solution pH of 4.4, a biosorbent dose of 2.0 g/L and a temperature of 22 °C, when over 88% of Cu(II), 76% of Co(II) and 81% of Zn(II) are removed by biosorption. The modeling of the obtained experimental data show that the Langmuir isotherm model and pseudo-second kinetic model well describe the biosorption processes of studied metal ions. The maximum biosorption capacity (qmax, mg/g) increases in the order: Cu(II) (64.52 mg/g) > Zn(II) (37.04 mg/g) > Co(II) (18.79 mg/g), while the minimum time required to reach the equilibrium is 60 min. Moreover, the regeneration efficiency of alginate is higher than 97% when a 10-1 N HNO3 solution is used as desorption agent for the recovery of Cu(II), Co(II) and Zn(II) ions. All these characteristics demonstrate that the alginate extracted from marine algae has promising applications in the decontamination of industrial effluent containing metal ions.