Palladium-Catalyzed Carbonylative Cross-Coupling Reaction of 1-Halo-1-alkenes with 9-Alkyl-9-BBN Derivatives. A Direct Synthesis of α,β-Unsaturated Ketones

Tatsuo Ishiyama; Norio Miyaura; Akira Suzuki

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Palladium-Catalyzed Carbonylative Cross-Coupling Reaction of 1-Halo-1-alkenes with 9-Alkyl-9-BBN Derivatives. A Direct Synthesis of α,β-Unsaturated Ketones

Ishiyama T
Miyaura N
Suzuki A

Bulletin of the Chemical Society of Japan (1991) 64(6) 1999-2001

DOI: 10.1246/bcsj.64.1999

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Abstract

The synthesis of α,β-unsaturated ketones by means of the palladium-catalyzed cross-coupling reaction between 9-alkyl-9-borabicyclo[3.3.1]nonanes (9-R-9-BBN) and 1-halo-1-alkenes under carbon monoxide atmosphere is described.

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Ishiyama, T., Miyaura, N., & Suzuki, A. (1991). Palladium-Catalyzed Carbonylative Cross-Coupling Reaction of 1-Halo-1-alkenes with 9-Alkyl-9-BBN Derivatives. A Direct Synthesis of α,β-Unsaturated Ketones. Bulletin of the Chemical Society of Japan, 64(6), 1999–2001. https://doi.org/10.1246/bcsj.64.1999

Palladium-Catalyzed Carbonylative Cross-Coupling Reaction of 1-Halo-1-alkenes with 9-Alkyl-9-BBN Derivatives. A Direct Synthesis of α,β-Unsaturated Ketones

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