Performances of Solid Oxide Cells with La 0.97 Ni 0.5 Co 0.5 O 3−δ as Air-Electrodes

Abstract

Based on previous studies of perovskites in the quasi-ternary system LaFeO 3 –LaCoO 3 –LaNiO 3 , La 0.97 Ni 0.5 Co 0.5 O 3 (LNC) is chosen as the most promising air-electrode material in the series for solid oxide cells (SOCs). The properties of the material itself have been investigated in detail. However, the evaluation of LNC97 air electrodes in practical SOCs is still at a very early stage. In the present study, SOCs were prepared based on LNC97 air electrodes. The I-U performance of the SOCs in both solid oxide fuel cell (SOFC) and solid oxide electrolysis cell (SOEC) modes, i.e. reversible SOCs (r-SOCs), was investigated systematically for different air-electrode designs, temperatures and fuel gases. In general, the performance of the r-SOCs tested in the present study is higher than the published results of other LaFeO 3 –LaCoO 3 –LaNiO 3 -based SOCs and is comparable to or even better than state-of-the-art La 1−x Sr x Fe 1−y Co y O 3 (LSCF)-based SOCs. Mid-term operation of about 1000 h for SOCs in both SOFC and SOEC modes primarily proved the stability of LNC97-based air electrodes. Impedance spectra were systematically applied to understand the polarization processes of the SOCs.