Catalytic dehydrocoupling of amine-boranes and amines into diaminoboranes: Isolation of a Pt(ii), Shimoi-type, η1-BH complex

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Abstract

The platinum complex [Pt(ItBu′)(ItBu)][BArF] is a very efficient catalyst in the synthesis of diaminoboranes through dehydrocoupling of amine-boranes and amines. Shimoi-type, η1-BH complexes are key intermediates in the process.

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Roselló-Merino, M., Rama, R. J., Díez, J., & Conejero, S. (2016). Catalytic dehydrocoupling of amine-boranes and amines into diaminoboranes: Isolation of a Pt(ii), Shimoi-type, η1-BH complex. Chemical Communications, 52(54), 8389–8392. https://doi.org/10.1039/c6cc02720b

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