Generation of polyyne and methylpolyyne molecules from toluene by intense femtosecond laser pulse irradiation

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Abstract

Hydrogen-capped and methyl-capped carbon chains (polyynes) have been generated by intense femtosecond laser irradiation of pure liquid toluene. UV-Vis and Raman spectroscopy were used to confirm the presence of polyynes in the irradiated samples, and high performance liquid chromatography (HPLC) was used to separate polyynes up to C18 H2 and HC13 CH3.

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Ramadhan, A., Wesolowski, M., Wakabayashi, T., Shiromaru, H., Fujino, T., Kodama, T., … Sanderson, J. (2015). Generation of polyyne and methylpolyyne molecules from toluene by intense femtosecond laser pulse irradiation. In Journal of Physics: Conference Series (Vol. 635). Institute of Physics Publishing. https://doi.org/10.1088/1742-6596/635/11/112125

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