Simple design to achieve red-to-near-infrared emissive cationic Ir(III) emitters and their use in light emitting electrochemical cells

Abstract

Two cationic Ir(iii) complexes bearing 2-phenylpyridinato cyclometalating ligands and bithiazole-type ancillary ligands have been synthesized and optoelectronically characterised. These emitters exhibit unusually deep red-to-near-infrared emission at room temperature, thereby rendering them as attractive emitters in solution-processed light emitting electrochemical cell (LEEC) electroluminescent devices.