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Copper-catalyzed hydrosilylation with a bowl-shaped phosphane ligand: Preferential reduction of a bulky ketone in the presence of an aldehyde

Angewandte Chemie - International Edition (2010) 49(8) 1472-1476
DOI: 10.1002/anie.200906348
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Abstract

Chemical Equation Presented Hollywood bowl: A highly active copper catalyst with a bowl-shaped phosphane (bsp) ligand was used in the hydrosilylation reaction of bulky ketones. The preferential reduction of a bulky ketone in the presence of an unprotected aldehyde is unprecedented. © 2010 Wiley-VCH Verlag GmbH &. Co. KGaA,.

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Fujihara, T., Semba, K., Terao, J., & Tsuji, Y. (2010). Copper-catalyzed hydrosilylation with a bowl-shaped phosphane ligand: Preferential reduction of a bulky ketone in the presence of an aldehyde. Angewandte Chemie - International Edition, 49(8), 1472–1476. https://doi.org/10.1002/anie.200906348

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