Light-triggered Supramolecular Isomerism in a Self-catenated Zn(II)-organic Framework: Dynamic Photo-switching CO 2 Uptake and Detection of Nitroaromatics

Abstract

A self-catenated Zn(II)-organic framework formulated as [Zn 2 (3,3′-bpeab)(oba) 2 ]·DMF (1) exhibiting a six-connected 4 4 ·6 10 ·8 topology has been successfully synthesized through the mixed-ligand of kinked 3,3′-bis[2-(4-pyridyl)ethenyl]azobenzene (3,3′-bpeab) and 4,4′-oxybis-benzoic acid (H 2 oba) under solvothermal condition. UV light triggers isomerization of complex 1 in a single-crystal-to-single-crystal (SCSC) manner, giving rise to a conformational supramolecular isomer 1-UV through the pedal motion of photoresponsive double bonds. Dynamic photo-switching in the obtained light-responsive supramolecular isomers leads to instantly reversible CO 2 uptake. Furthermore, the ligand originated fluorescence emission of water-resistant complex 1 is selectively sensitive to 4-nitrotoluene (4-NT) owing to a higher quenching efficiency of the perilous explosive over other structurally similar nitroaromatics, prefiguring the potentials of 1 as a fluorescence sensor towards 4-NT in aquatic media.