Fully reversible three-state interconversion of metallosupramolecular architectures

Nikita Mittal; Manik Lal Saha; Michael Schmittel

Journal ArticleOPEN ACCESS

Fully reversible three-state interconversion of metallosupramolecular architectures

Mittal N
Saha M
Schmittel M

Chemical Communications (2016) 52(56) 8749-8752

DOI: 10.1039/c6cc03824g

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Abstract

The reversible switching of a sterically encumbered phenanthroline-Cu+-picolinaldehyde trio back and forth between homoleptic and heteroleptic coordination using the relative metal-ion to ligand ratio is the basis for an unprecedented cyclic three-state interconversion of metallacycles.

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Mittal, N., Saha, M. L., & Schmittel, M. (2016). Fully reversible three-state interconversion of metallosupramolecular architectures. Chemical Communications, 52(56), 8749–8752. https://doi.org/10.1039/c6cc03824g

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Fully reversible three-state interconversion of metallosupramolecular architectures

Abstract

References Powered by Scopus

From supramolecular chemistry towards constitutional dynamic chemistry and adaptive chemistry

Recent Developments in the Preparation and Chemistry of Metallacycles and Metallacages via Coordination

Stimuli-Responsive Metal-Ligand Assemblies

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Palladium(II)-Based Self-Assembled Heteroleptic Coordination Architectures: A Growing Family

Donor-Site-Directed Rational Assembly of Heteroleptic cis-[Pd <inf>2</inf> L <inf>2</inf> L′ <inf>2</inf> ] Coordination Cages from Picolyl Ligands

Switchable metallacycles and metallacages

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