Abstract
Two synthetic strategies to the construction of heterobimetallic fulvalene (η5:η5-C10H8) complexes are reported. The first is based on the previously described monometallic ring-slippage products of (η5:η5-C10H8)Mo2-(CO)8and (η5:η5-C10H8)Ru2(CO)4that undergo recomplexation with a variety of metal carbonyls. The second utilizes a potentially iterative synthetic organic strategy in which cyclopentadienyl anion is subjected to an alkano-ylation–ring closure sequence that assembles a new attached cyclopentadiene unit. © 1986, American Chemical Society. All rights reserved.
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CITATION STYLE
Huffman, M. A., Newman, D. A., Tilset, M., Tolman, W. B., & Vollhardt, K. P. C. (1986). Designed Syntheses of Heterobimetallic Fulvalene Complexes. Organometallics, 5(9), 1926–1928. https://doi.org/10.1021/om00140a038
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