Direct synthesis of diallyl sulfides from allyl alcohols and hexamethyldisilathiane

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Abstract

Diallyl sulfides were obtained in 60-90% yields by reaction of various allyl alcohols (1.0 equiv) with hexamethyldisilathiane (≈0.55 equiv) in CH2Cl2 at room temperature in the presence of BF3·OEt2 (0.8-1.1 equiv). © 1993.

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Tsay, S. C., Yep, G. L., Chen, B. L., Lin, L. C., & Hwu, J. R. (1993). Direct synthesis of diallyl sulfides from allyl alcohols and hexamethyldisilathiane. Tetrahedron, 49(40), 8969–8976. https://doi.org/10.1016/S0040-4020(01)91216-5

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