Preparation of a novel zwitterionic striped surface thin-film composite nanofiltration membrane with excellent salt separation performance and antifouling property

Abstract

Thin-film composite (TFC) nanofiltration (NF) membranes were fabricated via the co-deposition of taurine, tannic acid (TA), and polyethyleneimine (PEI), followed by subsequent interfacial polymerization with trimesoyl chloride (TMC) on the surface of the polysulfone ultrafiltration substrates. The surface properties, including the roughness, hydrophilicity, surface potential, and NF performances were facilely tuned by varying the taurine content for the prepared TFC membranes. In addition, the as-prepared TFC NF membranes had an excellent antifouling property and flux recovery ratio (FRR) in humic acid (HA), bovine serum albumin (BSA) and sodium alginate (SA) filtration tests. These results also revealed that the taurine content controlled the formation of the striped surface. Thus, this work provided a viable strategy for fabricating TFC NF membranes with high selectivity and outstanding antifouling ability.