Abstract
Solid-state tunnel junction devices were fabricated from Langmuir Blodgett molecular monolayers of a bistable [2]catenane, a bistable [2]pseudorotaxane, and a single-station [2]rotaxane. All devices exhibited a (noncapacitive) hysteretic current-voltage response that switched the device between high- and low-conductivity states, although control devices exhibited no such response. Correlations between the structure and solution-phase dynamics of the molecular and supramolecular systems, the crystallographic domain structure of the monolayer film, and the room-temperature device performance characteristics are reported.
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CITATION STYLE
Collier, C. P., Jeppesen, J. O., Luo, Y., Perkins, J., Wong, E. W., Heath, J. R., & Stoddart, J. F. (2001). Molecular-based electronically switchable tunnel junction devices. Journal of the American Chemical Society, 123(50), 12632–12641. https://doi.org/10.1021/ja0114456
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