Metal-ligand interplay in strongly correlated oxides: A parametrized phase diagram for pressure-induced spin transitions

Abstract

We investigate the magnetic properties of archetypal transition-metal oxides MnO, FeO, CoO, and NiO under very high pressure by x-ray emission spectroscopy at the Kβ line. We observe a strong modification of the magnetism in the megabar range in all the samples except NiO. The results are analyzed within a multiplet approach including charge-transfer effects. The spectral changes are well accounted for by changes of the ligand field acting on the d electrons and allows us to extract the d-hybridization strength, O-2p bandwidth and ionic crystal field across the magnetic transition. This approach allows first-hand insight into the mechanism of the pressure-induced spin transition. © 2007 The American Physical Society.