Thermal and viscoelastic properties of novel epoxydicyclopentadiene- terminated polyesters-styrene copolymers

Abstract

This article presents the studies on the thermal and viscoelastic properties of novel epoxy-dicyclopentadiene-terminated polyesters-styrene copolymers. The novel materials were prepared during a three step process including the addition reaction of maleic acid to norbonenyl double bond of dicyclopentadiene; polycondensation of acidic ester of dicyclopentadiene, cyclohex-4-ene-dicarboxylic anhydride, maleic anhydride, and suitable glycol: ethylene, diethylene, or triethylene glycol; and the epoxidation process of prepared polyesters. It allowed obtaining novel epoxy-dicyclopentadiene- terminated polyesters which were successfully used as a component of different styrene content (10-80 mass%) copolymers. The influence of the structures of polyester and styrene content on the cross-linking density (ve), tgdmax, tgdmax height, storage modulus (E02°C), FWHM values as well as the thermal stability of copolymers was evaluated by TG, DSC, and DMA analyses and discussed. © The Author(s) 2012.