Abstract
A variety of aromatic compounds was regioselectively iodinated with iodine and F-TEDA in imidazolium- and pyridinium-based ionic liquids, [bmim][PF 6] and [bpyr][BF4]. Iodination was) para- directed when possible, otherwise it occurred in the ortho- position. The substrate selectivity measured in competitive experiments is in agreement with a polar mechanism.
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Chiappe, C., & Pieraccini, D. (2002). Regioselective iodination of arenes in ionic liquids mediated by theSelectfluorTM reagent F-TEDA-BF4. Arkivoc, 2002(11), 249–255. https://doi.org/10.3998/ark.5550190.0003.b22
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