Permanganyl Fluoride: A Brief History of the Molecule MnO3F and of Those Who Cared For It

Abstract

Permanganyl fluoride's existence at the stability threshold in the series of oxides and oxide fluorides of the late 3d transition metals is reflected by its experimentally challenging properties and by the difficulties posed in the theoretical description of its bonding characteristics. The history of this molecule is reviewed from early qualitative observations and the growing scattered information on its chemical and physical properties to the accurate determination and interpretation of its molecular structure and spectral features. The still problematic theoretical models for MnO4− and MnO3F are briefly presented in the broader context of the chemistry of elements in high oxidation states. Short biographies of the scientists engaged in these studies are offered. Related technetium and rhenium compounds are briefly considered for comparison.