Abstract
Hydrophosphination of styrenes has been accomplished with metal salts for the first time. (CuOTf)2·toluene complex is the catalyst of choice, but CuCl can also be used. "In-situ" EPR and NMR studies suggest Cu(I) as the catalytically active metal species, giving exclusively the anti-Markovnikov product. Phosphine oxides or β-ketophosphine oxides can be prepared in one-pot by oxidation with molecular oxygen. © 2010 Elsevier B.V. All rights reserved.
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Leyva-Pérez, A., Vidal-Moya, J. A., Cabrero-Antonino, J. R., Al-Deyab, S. S., Al-Resayes, S. I., & Corma, A. (2011). Copper(I)-catalyzed hydrophosphination of styrenes. Journal of Organometallic Chemistry, 696(1), 362–367. https://doi.org/10.1016/j.jorganchem.2010.09.069
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