An organometallic sandwich lanthanide single-ion magnet with an unusual multiple relaxation mechanism

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Abstract

A dysprosium(III) sandwich complex, [DyIII(COT″) 2Li(THF)(DME)], was synthesized using 1,4-bis(trimethylsilyl) cyclooctatetraenyl dianion (COT″). The complex behaves as a single-ion magnet and demonstrates unusual multiple relaxation modes. The observed relaxation pathways strongly depend on the applied static dc fields. © 2011 American Chemical Society.

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Jeletic, M., Lin, P. H., Le Roy, J. J., Korobkov, I., Gorelsky, S. I., & Murugesu, M. (2011). An organometallic sandwich lanthanide single-ion magnet with an unusual multiple relaxation mechanism. Journal of the American Chemical Society, 133(48), 19286–19289. https://doi.org/10.1021/ja207891y

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